This will depend on how your network is configured, there are two likely scenarios that I can think of:
- Your web server is behind a router and port 80 is forwarded
- Your web server has it's own IP address on the internet
In the first instance you shouldn't have to do anything unless you want to access the website using a URL (e.g. www.mywebserver.com) in which case you'll have to play some DNS tricks on the local network to get it to point to the local IP of the server instead of the actual internet IP. For example when accessed from the internet the dns record for www.mywebserver.com would point to 12.34.56.78 where as the dns record for any machine on the local network would be something like 192.168.0.10.
In the second case to my knowledge there is nothing you can do that will allow you to be able to access on the intranet (I could be wrong so if someone posts a solution in this case I'll update my answer).
So the answer to your question really depends on your network configuration, If you expand on that a little giving a more concrete answer will be a little easier.