First of all, you shouldn't compare to boolean values, this is, do
if condition then
instead of
if condition = true then
About your question, it depends on the natural variable names, IMO.
For example, if you are creating a client that needs to check if it's connected (the most common case)
if connected then
//Proceed
else
//Throw error
end if
Or, if you are creating a different program, where you have a variable, say, retrieved and you want to know if the content has been retrieved
if not retrieved then
//Error
end if
Do not do
if retrieved then
else
//Error
end if