Put the values in an array, reverse sort it using rsort() and then take the first two:
$values = array('01-blahbla.php', '02-sdfsdff.php', '03-aaaaaaa.php', '04-bbbbbbb.php', '05-wwwwwwi.php');
rsort($values);
$file1 = $values[0];
$file2 = $values[1];
require_once $file1;
require_once $file2;
The PHP manual at php.net has some great info for the various sort methods.
Update:
As Psytronic noted, rsort will not work for numbers, but you can create a custom function that easily does the same thing:
function rnatsort(&$values) {
natsort($values);
return array_reverse($values, true);
}
$files = rnatsort($values);