Try this:
Sub AddButtonAndShow()
Dim Butn As CommandButton
Dim Line As Long
Dim objForm As Object
Set objForm = ThisWorkbook.VBProject.VBComponents("UserForm1")
Set Butn = objForm.Designer.Controls.Add("Forms.CommandButton.1")
With Butn
.Name = "CommandButton1"
.Caption = "Click me to get the Hello Message"
.Width = 100
.Top = 10
End With
With objForm.CodeModule
Line = .CountOfLines
.InsertLines Line + 1, "Sub CommandButton1_Click()"
.InsertLines Line + 2, "MsgBox ""Hello!"""
.InsertLines Line + 3, "End Sub"
End With
VBA.UserForms.Add(objForm.Name).Show
End Sub
This permanently modifies UserForm1 (assuming you save your workbook). If you wanted a temporary userform, then add a new userform instead of setting it to UserForm1. You can then delete the form once you're done with it.
Chip Pearson has some great info about coding the VBE.