In normal Silverlight apps if the root element is stretched (horizontally ad vertically) it will take up the entire Silverlight browser object.
With a Sketchflow application the root visual is a Microsoft.Expression.Prototyping.Workspace.PlayerWindow and your screens are dynamically displayed within a frame on the right side.
As shown above the size of the frame seems to only be defined by the content. If no size is specified in the client, the content will shrink to its minimum size. Setting the HorizontalContentAlignment or VerticalContentAlignment of the player has no effect (no surprise as it has multiple child controls) and I have not been able to find any references relating to changing the PlayerWindow.
It would be preferable to template the PlayerWindow control, but that template is not recognised by Expression Blend so only shows the Create Empty template option. Anyone know where/how to find and extract the generic template for the PlayerWindow?
Update 13 Sep 2010
I have been examining the internals of the PlayerWindow (using .Net Reflector) and it was not built to be a templated control (shame). That means any solutions will likely have to dig into the Xaml element tree directly (or replace the PlayerWindow in its entirety!).