One of the most common kinds of database table has an alphanumeric code and human friendly name (e.g. countries, currencies, accounts, products, VAT codes etc.)
The traditional/obvious thing to do is make the code the primary key. And for some tables e.g. customers where the number may be large so that names may not be unique identifiers, this is clearly the correct thing to do.
But what about things like countries and currencies where the number is guaranteed to be small and the names are guaranteed to be unique? In that case, references will almost always be both input and displayed with the human friendly name.
In that scenario, is there any reason not to make the name the primary key?