I did this using madExcept. It's really useful for tracking down problems we couldn't reproduce ourselves.
Which makes me ask why you are getting so many? Untrapped exceptions should be few and far between. Especially if the user sees an error dialog. I was responsible for several applications, each with hundreds of installs and I would rarely get e-mail notices.
If they are mostly from a very small number of PCs, I'd work with some of those users to find out what they're doing differently, or how their setup might be generating exceptions.
If they are from all over the place, it's probably a bug that got through your testing.
Either way, use the details to fix your code or, at the very least, anticipate known exceptions and trap them properly (no empty try..except).
Fixing the hot spot problems will cut way down on the number of e-mails you get, making the occasional notice much more manageable.