We were trying to avoid ctrl-n javascript hooks
Forget it. Whilst you could in theory try to catch keypress events for ‘n’ with the Control key modifier, there are any number of other ways to open a new window or tab which may be more likely to be used, and you won't be able to catch. File->New Window/Tab, middle click or shift-click link, middle click back/forward buttons, right-click-open-in-new-window, open bookmark in new tab, double-click browser icon...
The user is already authenticated and we make heavy use of sessions.
That shouldn't be a problem in itself. I guess what you mean is that your application is dumping all sorts of page-specific data in the session that it shouldn't have, and now you find the application breaks when you have more than one window open on it? Well, commiserations and happy rewriting.
In the meantime about all you can do is tell the user “please don't try to open two browser windows on the same application”. There are potential ways you can make JavaScript on one page notice that JavaScript is running on another page in the same domain at the same time, generally involving using document.cookie as a inter-page communications conduit. But that's also a bit fragile.