A: 

I just tried using blend 1.0. This version also had other options, such as 'infer xml schema'.

My guess is that there was some check added in later version to ensure that the file pointed to has an extension.

My suggestion is to edit the xaml directly. Note, this is old XAML from blend 1.0:

<Window.Resources>
 <XmlDataProvider x:Key="rssDS" d:IsDataSource="True" Source="http://www.tanguay.info/web/rss/"/&gt;
</Window.Resources>

Hope that helps, let me know.

Klathzazt
I put the same xml at http://www.tanguay.info/web/rss/test.xml and but typing that in as the URL doesn't make the OK button non-gray, I can read in this file locally fine, I'm on Vista, perhaps some firewall thing where I have to open something up.
Edward Tanguay