They're actually really similar. How you call them is exactly the same, but the difference lies in how the browser loads them into the execution context.
function declarations loads before any code is executed.
While function expressions loads only when the interpreter reaches that line of code.
So if you try to call a function expression before it's loaded, you'll get an error
But if you call a function declaration, it'll always work. Cuase no code can be called until all declarations are loaded.
ex. Function Expression
alert(foo()); // ERROR! foo wasn't loaded yet
var foo = function() { return 5; }
ex. Function Declaration
alert(foo()); // Alerts 5. Declarations are loaded befoer any code can run.
function foo() { return 5; }
As for the second part of your questions.
var foo = function foo() { return 5; } is really the same as the other two. It's just that this line of code used to cause an error in safari. I'm not sure if it still does. Haven't tried.