From your description, it sounds like a simple matrix operation. You just have to make sure you have the right dimensions for C and S. C should be a column vector (length(C)-by-1) and S should be a row vector (1-by-length(S)). Assuming they are the right dimensions, just do the following:
mat = C*S;
If you're not sure of their dimensions, this should work:
mat = (C(:))*(S(:)');
EDIT: Actually, I went a little crazy with the parentheses. Some of them are unnecessary, since there are no order-of-operation concerns. Here's a cleaner version:
mat = C(:)*S(:)';
EXPLANATION:
The matrix multiplication operator in MATLAB will produce either an inner product (resulting in a scalar value) or an outer product (resulting in a matrix) depending on the dimensions of the vectors it is applied to.
The last equation above produces an outer product because of the use of the colon operator to reshape the dimensions of the vector arguments. The syntax C(:) reshapes the contents of C into a single column vector. The syntax S(:)' reshapes the contents of S into a column vector, then transposes it into a row vector. When multiplied, this results in a matrix of size (length(C)-by-length(S)).
Note: This use of the colon operator is applicable to vectors and matrices of any dimension, allowing you to reshape their contents into a single column vector (which makes some operations easier, as shown by this other SO question).