The identity column cannot(corrected based on feedback from @AlexKuznetsov) should not have duplicates within the column itself - it is generally meant to be a unique column and a provide non-identifying value for each row.
If you are asking how to put values into the identity column that already exist in another column, you have to do the following:
Set IDENTITY_INSERT Schema.TableName ON
Insert Into TableName (PK1, PK2, IdentityCol1, OtherCol1, OtherCol2)
SELECT FirstCol, SecondCol, SecondCol, OtherColumn1, OtherColumn2
FROM SomeOtherTable
Set IDENTITY_INSERT Schema.TableName OFF
note that PK2 and IdentityCol1 both get the same value