You may find an article such as this useful.
My way of thinking. You have general description of the use cases, so you know what the system you're building is supposed to do. But those use cases no doubt have lots of wrinkles and special cases. [In passing "Manage Students" seems at a rather different granularity from "Appoint Teacher" susepect you need "Enrol Student", "Suspend Student", "Graduate Student" or some such.]
So your next step is to capture more of the requirements of the system by giving more detail of the use cases. You express that in terms of actions by people and systems. Do you have a system context diagram or some such? This would show everything your system interacts with. You then express your scenarios as a sequence of actions by actors, your system and other systems.
The Teacher logs on
TheSystem presents a menu
The Teacher selects "record grade"
The System presents a list of classes taught by the teacher
The Teacher selects class
etc.
The wrinkles come from considering the variations that might occur. Any special actions for failing grades? Restrictions on grading for certain types of students? So you create additional scenarios for such "interesting" cases.
In my understanding, at this stage specfic classes and class diagrams are not needed. Later you can consider one step such as "The system presents a list of classes taugh by the teacher" and consider how the system implements that using your class diagram.
Remember the objective here: get the complete picture of the requirements you need to satisfy.