Just to be very clear: those things in an XML document that look like a URL, and that you see in:
xmlns="http://schemas.microsoft.com/cdo/configuration/smtpauthenticate"
or
xmlns:cdo="http://schemas.microsoft.com/cdo/configuration/smtpauthenticate"
Those are not URLs. They do not mean that .NET is going to access a location on the Internet when you are using the document. In particular, it is impossible for one of these things (which are called XML Namespaces, by the way), to be the cause of your problem.
As lavinio said above, post the complete exception and maybe you'll get some help. You should put a try/catch block around the code having the problem, catch the exception in, for instance, "ex", then post the result of ex.ToString().