When I first looked at the problem, my initial view was that the char 'c' should be shifted left 8 bits - all 8 bits being discarded, the empty char would then be cast to an int of value 0.
A bit of research reveals Usual Unary Conversions - this is where to reduce the large number of arithmetic types, conversions are applied automatically to operands of the unary '!', '-', '~' and '*' operators, and to each of the operands of the binary '<<' and '>>' operators.
Therefore the char 'c' is converted to and int first, then shifted left, giving the answer you see.
You learn something new every day!