You are probably looking for FormattedText.BuildGeometry Method
or FormattedText.BuildHighlightGeometry Method
; both MSDN links are featuring the usual examples too.
The basic usage pattern is like so:
// Create sample formatted text.
FormattedText formattedText = new FormattedText("Sample",
CultureInfo.GetCultureInfo("en-us"), FlowDirection.LeftToRight,
new Typeface("Verdana"), 16, System.Windows.Media.Brushes.Black);
// Build geometry object that represents the text.
Geometry normalGeometry = formattedText.BuildGeometry(
new System.Windows.Point(0, 0));
// Build geometry object that represents the highlight bounding box of the text.
Geometry highLightGeometry = formattedText.BuildHighlightGeometry(
new System.Windows.Point(0, 0));