"Materialized path" as presented by Vadim Tropashko in that article, introduces the notion of order into a relation ("Jones is the second member".).
"Materialized path" is nothing but "some form of materialized view" on the transitive closure, and therefore suffers all and exactly the same problems as any other "materialized view", except that matters are algorithmically worse precisely because of the involvement of a closure.
SQL is almost completely powerless when constraints-on-a-closure are in play. (Meaning : yes, SQL requires you to do everything yourself.) It's one of those areas where the RM shows the maximum of its almost unlimited power, but SQL fails abysmally, and where it is such a shame that the majority of people mistake SQL for being relational.
(@Bill Karwin : I'd like to be able to give you +1 for your remark on the relation between the depth of the trees and the result on performance. There are no known algorithms to compute closures that perform well in the case of trees with "crazy" depths. It's an algorithmic problem, not an SQL nor a relational one.)
EDIT
Yes, RM = Relational Model