You could do this. Refer to this MSDN article
<configuration>
<configSections>
...
<section name="unity" type="Microsoft.Practices.Unity.Configuration.UnityConfigurationSection, Microsoft.Practices.Unity.Configuration" />
...
</configSections>
...
<unity>
<typeAliases>
<!-- Lifetime manager types -->
<typeAlias alias="singleton" type="Microsoft.Practices.Unity.ContainerControlledLifetimeManager, Microsoft.Practices.Unity" />
<typeAlias alias="external" type="Microsoft.Practices.Unity.ExternallyControlledLifetimeManager, Microsoft.Practices.Unity" />
<typeAlias alias="ILoginService" type="Company.Shared.ILoginService,Company.Shared.Interface" />
<typeAlias alias="LoginService" type="Company.Server.LoginService,Company.Server.Core" />
<typeAlias alias="INavigationService" type="Company.Shared.INavigationService,Company.Shared.Interface" />
<typeAlias alias="NavigationService" type="Company.Server.NavigationService,Company.Server.Core" />
</typeAliases>
<containers>
<container name="Services">
<types>
<type type="ILoginService" mapTo="LoginService" />
<type type="INavigationService" mapTo="NavigationService" />
</types>
</container>
</containers>
</unity>
....
UPDATE: If you look into the MSDN article, there is a section that describes what I believe that fits your requirements.
<type type="IMyService" mapTo="MyDataService" name="DataService">
<typeConfig extensionType="Microsoft.Practices.Unity.Configuration.TypeInjectionElement,
Microsoft.Practices.Unity.Configuration">
<constructor>
<param name="connectionString" parameterType="string">
<value value="AdventureWorks"/>
</param>
<param name="logger" parameterType="ILogger">
<dependency />
</param>
</constructor>
</typeConfig>
</type>