Well, I do not know if that is applicable to your scenario but you could simply rotate the horizontal line using LayoutTransform and the gradient will be okay.
<Line HorizontalAlignment="Stretch" VerticalAlignment="Center"
Stretch="Uniform" StrokeThickness="5" X1="0" Y1="0" X2="1" Y2="0">
<Shape.Stroke>
<LinearGradientBrush StartPoint="0,0" EndPoint="0,1">
<GradientStop Color="Transparent" Offset="0" />
<GradientStop Color="Green" Offset="0.5" />
<GradientStop Color="Transparent" Offset="1" />
</LinearGradientBrush>
</Shape.Stroke>
<Line.LayoutTransform>
<RotateTransform Angle="40"/>
</Line.LayoutTransform>
Milan Nankov
2009-09-11 20:17:02