The following applies to Jet 4.0 only, being the version of the Access Database Engine in the era Access2000 to Access2003 inclusive:
I wouldn't store any of the documents in the database, but store the data in files in the file system, and the only thing that's in the database would be a pointer to the data files.
You don't give any details in your question that would suggest any need whatsoever to store the documents in the database itself.
And there are very few circumstances where it's advantageous.
If you are using ACE, being the version of the Access Database Engine in the Access2007 era, the Attachment data type would be an option, however I don't really know how it works, I've never used it so I can't recommend it nor say whether it's better or worse for this purpose. I'm also wary of new data types in the first release of a major version of the Access Database Engine. I just remember all the issues with byte and decimal fields at the introduction of Jet 4 and don't want to commit to something that may never work properly. The Attachment type in the ACCDB format was introduced for Sharepoint compatibility, and that outside dependency is something that gives me pause. Will the ACCEDB data type change someday if Sharepoint changes the way it works? I'm not sure I'd want to take that risk.