The simplest solution is to use the DateTime.DayOfWeek property (http://msdn.microsoft.com/en-us/library/system.datetime.dayofweek.aspx).
You start with getting today's date, or, if today is Monday and you can't deliver for two days, so the next delivery will be a week Monday, then start with tomorrow. I am not certain how you would handle if I order tomorrow could I get a delivery date for the next day, so I would need that clarified.
Get the day of the week, starting with either today or tomorrow, extracting it from a specific date as explained here:
http://msdn.microsoft.com/en-us/library/system.datetime.dayofweek.aspx
If it isn't Monday or Tues then just determine how many days you need to reach Monday or Tuesday, then add that number of days and get that date, and then just add seven and get the date.
I would prefer to let .NET determine the date of seven days from now, as you may change month or years.
That is the basic approach. If you get stuck when trying to implement it, I would suggest some code so we can help you determine where you got stuck.
There are other approaches, but this is probably the simplest to understand and implement.