There was a time when the marketing guys at Microsoft were sticking the suffix ".NET" on to every MS product they could. Sometimes it made sense - e.g. to distinguish VB 6.0, and earlier versions, from what came after. Other times it was just marketing phooee; at one point I think they were going to rechristen all the server products with the .NET suffix: Windows.NET Server, SharePoint.NET Services etc.
But it was a short-lived phenomenon and quickly dropped (in some cases before the products were actually launched).
In the case of C#, there was no earlier version and only later the prospect of publishing the spec and seeing other implementations, so it made little difference whether it was called C#.NET or just C#.
I guess that's just marketing guys for you - they did exactly the same with the "Active" prefix before that...