You should use an ORM as long as you need to convert database data to and from business objects, since it will save you a lot of work and will allow you to focus on your application logic.
NHibernate is a .NET library that does just that, mapping .NET objects to database tables according to how you configure it. In this sense it is the same as the Entity Framework, only that EF is already embedded in the .NET framework and NHibernate is a separate assembly that you must reference in your project.
Last but not least, if you use SQL Server you should add LINQ to SQL to the list of possible ORM candidates, it is simpler that EF and for many scenarios it is more than appropriate.