MDX is the query language developed by Microsoft for use with their OLAP tools. Since its creation, others (The open source project Mondrian, and Hyperion) have tried to create versions of it for use in their products.
OLAP data tends to look like a star-schema with a central fact table surrounded by multiple dimensions. MDX is designed to allow you to query these structures and create cross-tab type results.
While the language looks like SQL it doesn't behave like it and if you are an SQL programmer, the mental leap can be tough.
As to whether it is better than SQL, it serves a highly specialized purpose, i.e. analyzing data in a specific format. So if you want to query a star schema, it is better, otherwise, SQL will probably do the job.