I define a simple Bug Class:
using System;
namespace BugNS.Entities
{
    class Bug
    {
        public virtual int Id { get; private set; }
        public virtual int BugNumber { get; set; }
    }
}
and a simple mapper class:
using System;
using FluentNHibernate.Mapping;
using BugNS.Entities;
namespace BugNS.Mappings
{
    class BugMap : ClassMap<Bug>
    {
        public BugMap()
        {
            Id(b => b.Id);
            Map(b => b.BugNumber);
        }
    }
}
and then just try to use it like:
using System;
using System.IO;
using FluentNHibernate.Cfg;
using FluentNHibernate.Cfg.Db;
using NHibernate;
using NHibernate.Cfg;
using NHibernate.Tool.hbm2ddl;
using BugNS.Entities;
namespace BugNS
{
    class Program
    {
        private const string DbFile = "bugs.db";
        static void Main()
        {
            var sessionFactory = CreateSessionFactory();
            using (var session = sessionFactory.OpenSession())
            {
                using (var transaction = session.BeginTransaction())
                {
                    Bug b = new Bug { BugNumber = 121212 };
                    session.SaveOrUpdate(b);
                    transaction.Commit();
                }
            }
        }
        private static ISessionFactory CreateSessionFactory()
        {
            return Fluently.Configure()
                .Database(SQLiteConfiguration.Standard
                    .UsingFile(DbFile))
                .Mappings(m =>
                    m.FluentMappings.AddFromAssemblyOf<Program>())
                .ExposeConfiguration(BuildSchema)
                .BuildSessionFactory();
        }
        private static void BuildSchema(Configuration config)
        {
            // delete the existing db on each run
            if (File.Exists(DbFile))
                File.Delete(DbFile);
            // this NHibernate tool takes a configuration (with mapping info in)
            // and exports a database schema from it
            new SchemaExport(config)
              .Create(false, true);
        }
    }
}
and I got the following error:
An unhandled exception of type 'NHibernate.MappingException' occurred in NHibernate.dll
Additional information: No persister for: BugNS.Entities.Bug
I am sorry, but I just started learning Fluent and NHibernate from the docs. It would be great if someone knows the solution to this issue, as I already spend many hours in vain.