I would actually recommend attacking NHib from a totally Fluent perspective right now - FNH has matured just enough to not drive you nuts with inconsistencies, there are a lot of decent learning aids out there (try and look at anything posted since Sep 2009 on at first), as well as a decently active user group.
I found this amazingly good and very recent video tutorial Vacation of Fluent NHibernate, conceptually based on the Summer of NHib series everyone else has here. Unfortunately the author just got a new job and hasn't yet completed the series, but I will be shocked if you don't find it incredibly approachable and useful as a learning tool all the same.
You also can fairly easily learn to generate the HBM maps, and reading them is way more useful IMO, and certainly less painful, than writing them at first.
Lastly, give yourself a break and don't expect to master any of this by the end of the week! If you spend some time with FNH first, you will know which areas of NHib you want to dig into eventually and feel less overwhelmed by it when you do.
Cheers,
Berryl