How important communication and people skills are.
In college, you can walk away from the people you don't like or don't understand. You get together with your clique and friends. Others you don't like you just avoid, or you may decide to pick on them or even get in a fight with them or the other clique.
At work, you are expected to work with everyone on a professional level. You are expected to put a certain amount of your self-centered ego aside, and be polite, forthcoming, accurate, factual, friendly, helpful to the people you work with. Most of all: not taking things personal nor making your job a personal issue. Not talking behind the backs of others about their bad work, bad mouth, bad behavior, bad smell, bad ideas.
That's not something one necessarily learns in school or college. To the contrary.
Over time, you will find that there will be people around you that you like personally but actually are nothing but trouble for your job. There's people so grumpy you don't even want to approach them, but yet your job requires that the two of you sit together several times a week. There's people who would totally agree with you but you spend a full ten minutes discussing a subject without realizing that you want the same thing, you're just expressing ideas differently. There will be people that will give you a scary feeling simply by entering the room, and you'll be relieved it's someone else they want to talk to. There will be the factual leader who gives you the feeling he's setting you up for failure, questioning you and you get nervous every time he's only walking by. There will be the jerk who is actually kind of nice, but whenever you're spending lunch together you can't help but think that the others may look down upon you just by being his company. There's of course the guy who is intimidating, shouting in meetings, placing the blame. You don't want to get anywhere near him when he's "in a mood". But you have to.
These are just some of the social situations you will find yourself in when you pick up a job.