To answer some of your other questions:
Is visual studios team suite worth the time/money?
How much do you have? If you are a large company with a big budget and development staff and you are focused on Microsoft technologies than I would say yes. If you answered no to any of these questions, I would go the Open Source Route (Svn or GIT, Cruise Control or Team City, MsBuild, etc.)
We are moving from regular 2.0 webforms with no testing to TDD MVC and I need to know the lowdowns as in I've never made such a jump before (not that its a huge jump but I'm a nooby programmer that has just graduated college).
This is a good time for you to learn MVC then since you don't have a deep investment in Web Forms knowledge and MVC is a much better model for someone like you to master. TDD is not something that you will learn over night but stick with it and you will become a much better programmer because of it.