Did you mean "Complex" as in complex number with real and imaginary parts? This seems unlikely, so if not you'd have to give an example since "complex" means nothing specific in terms of the C language.
You will get a direct memory copy of the structure; whether that is what you want depends on the structure. For example if the structure contains a pointer, both copies will point to the same data. This may or may not be what you want; that is down to your program design.
To perform a 'smart' copy (or a 'deep' copy), you will need to implement a function to perform the copy. This can be very difficult to achieve if the structure itself contains pointers and structures that also contain pointers, and perhaps pointers to such structures (perhaps that's what you mean by "complex"), and it is hard to maintain. The simple solution is to use C++ and implement copy constructors and assignment operators for each structure or class, then each one becomes responsible for its own copy semantics, you can use assignment syntax, and it is more easily maintained.