The generic data provided is rather vague, so I will provide my own to demonstrate (with field names on the first line)
"EmployeeName","WeekNumber","DayOfWeek","HoursWorked"
"John Doe",20,"Monday",8
"John Doe",20,"Tuesday",8
"John Doe",20,"Wednesday",8
"John Doe",21,"Thursday",8
"John Doe",21,"Friday",8
"Jane Doe",20,"Monday",8
"Jane Doe",20,"Tuesday",8
"Jane Doe",21,"Wednesday",8
"Jane Doe",21,"Thursday",8
"Jane Doe",21,"Friday",8
Assuming that I read the question correctly, you would want the report to look like this:
John Doe
Week: 20
Monday 8 hours
Tuesday 8 hours
Wednesday 8 hours
Week: 21
Thursday 8 hours
Friday 8 hours
Jane Doe
Week: 20
Monday 8 hours
Tuesday 8 hours
Week: 21
Wednesday 8 hours
Thursday 8 hours
Friday 8 hours
If this is the case, you would group by the "EmployeeName" field first, and then simply add another group for "WeekNumber" via the Insert menu using the Group option. This is pretty straightforward, and you can do summaries on the fields at various levels. The only thing that would get "hairy" with multiple tier of grouping would be if you were calculating fields within the group and wanted to return those calculations to a higher level of grouping for summation, which would require declaring global variables within the report.
For what it's worth, I've been using Crystal Reports heavily for the past 7 years.