If the script, or service, that the form submits the values to is available via the internet then anyone, anywhere, can write a script that will submit values to it. So: yes, sanitize all inputs received.
The most basic model of web-security is pretty simple:
Do not trust your users
It's also worth linking to my answer in another post (Steps to become web-security savvy): http://stackoverflow.com/questions/1704333/steps-to-become-web-security-savvy/1705146#1705146.
I can't believe I answered without referring to the title-question:
Is there any reason to sanitize user input to prevent them from cross site scripting themself?
You're not preventing the user's being cross-site scripted, you're protecting your site (or, more importantly, you're client's site) from being the victim of cross-site scripting. If you don't close known security holes because you couldn't be bothered it will become very hard to get repeat business. Or good word-of-mouth advertising and recommendation from previous clients.
Think of it less as protecting your client, think of it -if it helps- as protecting your business.