In order to open it in any external application, you'll need to write the bytes to disk, then use Process.Start to launch the associated application on the temporary file. Just pass the temporary filename (with the appropriate extension) as the only argument the Process.Start, and it will open that file in the appropriate application.
Some applications may have a way to feed a stream of bytes, but this would need to be handled by the target application explicitly.
For sample code, you could do something like:
byte[] filedata = GetMyByteArray();
string extension = GetTheExtension(); // "pdf", etc
string filename =System.IO.Path.GetTempFileName() + "." + extension; // Makes something like "C:\Temp\blah.tmp.pdf"
File.WriteAllBytes(filename, filedata);
var process = Process.Start(filename);
// Clean up our temporary file...
process.Exited += (s,e) => System.IO.File.Delete(filename);