My first thought when seeing this is why do you really want to do this? This smells a little spoiled, kinda like milk does after being a few days expired.
What is the scenario that requires that these two seq stay at the same value?
Ignoring the "this seems a bit odd" feelings I'm getting in my stomach you could try this:
Put a trigger on table_a that does this on insert.
--set b seq to the value of a.
select setval('table_b_seq',currval('table_a_seq'));
The problem with this approach is that is assumes only a insert into table_a will change the table_a_seq value and nothing else will be incrementing table_a_seq. If you can live with that this may work in a really hackish fashion that I wouldn't release to production if it was my call.
If you really need this, to make it more robust make a single interface to increment table_a_seq such as a function. And only allow manipulation of table_a_seq via this function. That way there is one interface to increment table_a_seq and you should also put
select setval('table_b_seq',currval('table_a_seq'));
into that function. That way no matter what, table_b_seq will always be set to be equal to table_a_seq. That means removing any grants to the users to table_a_seq and only granting them execute grant on the new function.