In C, when you used the name of an array in an expression (including passing it to a function), unless it is the operand of the address-of (&) operator or the sizeof operator, it decays to a pointer to its first element.
That is, in most contexts array is equivalent to &array[0] in both type and value.
In your example, my_array has type char[100] which decays to a char* when you pass it to printf.
&my_array has type char (*)[100] (pointer to array of 100 char). As it is the operand to &, this is one of the cases that my_array doesn't immediately decay to a pointer to its first element.
The pointer to the array has the same address value as a pointer to the first element of the array as an array object is just a contiguous sequence of its elements, but a pointer to an array has a different type to a pointer to an element of that array. This is important when you do pointer arithmetic on the two types of pointer.
pointer_to_array has type char * - initialized to point at the first element of the array as that is what my_array decays to in the initializer expression - and &pointer_to_array has type char ** (pointer to a pointer to a char).
Of these: my_array (after decay to char*), &my_array and pointer_to_array all point directly at either the array or the first element of the array and so have the same address value.