JOINS are used to JOIN tables together with related information.
Tipical situations are where you have lets say
A user table where the user has specific security settings. The join would be used such that you can determine which settings the user has.
Users
-UserID
-UserName
UserSecurityRoles
-UserID
-SecurityRoleID
SecurityRoles
-SecurityRoleID
-SecurityRole
SELECT *
FROM Users u INNER JOIN
UserSecurityRoles usr ON u.UserID = usr.UserID INNER JOIN
SecurityRoles sr ON usr.SecurityRoleID = sr.SecurityRoleID
WHERE sr.SecurityRole = 'Admin'
LEFT joins will be used in the cases where you wish to retrieve all the data from the table in the left hand side, and only data from the right that match.
JOINS are used when you start normalizing your table structure. You can crete a table with 100s on columns, where a lot of the data could possibly be NULL, or you can normalize the tables, such that you avoid having too many columns with null values, where you group the appropriate data into table structures.
The answer to this Question has a VERY good link that has graphical display of using JOINs