As Jimmy Cuadra suggested, you could change the position of the div then add an overlay under it... This is similar to what jQuery Tools Expose does.
You don't really need a plugin to do this though, I answered another question with a similar approach. This script will remove the overlay if you click anywhere outside of the highlighted div. Note this requires you to use jQuery version 1.4+
// Relatively position the div to highlight
$('#myDiv').css({
position: 'relative',
top : 0,
left : 0,
zIndex : 100
});
// Add overlay and make clickable
var w = $(window).width();
var h = $(window).height();
var $overlay = $('<div/>', {
'id': 'overlay',
css: {
position : 'absolute',
height : h + 'px',
width : w + 'px',
left : 0,
top : 0,
background : '#000',
opacity : 0.5,
zIndex : 99
}
}).appendTo('body');
// Click overlay to remove
$('#overlay').click(function(){
$(this).remove();
})