The DMS Software Reengineering Toolkit can do this with C# 2/3/4.
DMS has compiler accurate parsers for C# (as well as Java and many other languages).
It automatically builds full Abstract Syntax Trees for whatever it parses. Each AST node is stamped with file/line/column for the token that represents that start of that node,
and the final column can be computed by a DMS API call. It attaches comments to tree nodes so they aren't lost. DMS can also regenerate valid code from the AST, or from a modified AST; this enables it to be used for code modification or generation.
It has a built-in option to generate XML from the ASTs, complete with node type, source position (as above), and any associated literal value. The command line call is:
run DMSDomainParser ++XML <path_to_your_file>
DMS itself provides a vast amount of infrastructure for manipulating the ASTs it builds:
traversing, pattern matching (against patterns coded essentially in source form), source-to-source transforms.
It has control flow, data flow, points-to analysis, global call graphs for C, COBOL and Java; that's all coming for C#.
DMS was designed to be a better solution than XML for manipulating such code.