Yes, both will give you deferred execution.
The difference is that IQueryable<T> is the interface that allows LINQ-to-SQL (LINQ.-to-anything really) to work. So if you further refine your query on an IQueryable<T>, that query will be executed in the database, if possible.
For the IEnumerable<T> case, it will be LINQ-to-object, meaning that all objects matching the original query will have to be loaded into the database.
In code:
IQueryable<Customer> custs = ...;
// Later on...
var goldCustomers = custs.Where(c => c.IsGold);
That code will execute SQL to only select gold customers. The following code, on the other hand, will execute the original query in the database, then filtering out the non-gold customers in the memory:
IEnumerable<Customer> custs = ...;
// Later on...
var goldCustomers = custs.Where(c => c.IsGold);
This is quite an important difference, and working on IQueryable<T> can in many cases save you from returning too many rows from the database. Another prime example is doing paging: If you use Take and Skip on IQueryable, you will only get the number of rows requested; doing that on an IEnumerable<T> will cause all of your rows to be loaded in memory.