Poison message / dead letter message queues are used to place messages that have been determined to be undeliverable in a queue that will not try to deliver them anymore. You would do this if you might want to manually take a look at failed messages and process them at a later point. You use these type of queues when you want to keep bad messages from degrading the performance of your system by retrying over and over again.
On the other hand, a response service would be used to notify the sender that there was an error processing the message. Typically in this case you aren't planning on manually processing the bad message and need to let the system that sent the message in that the request has been rejected.
Note that these aren't exclusive. If you are using queues, there is always the chance that the message serialization might change enough to break messages that are in the queue in which case you might still want to have a dead letter queue even if you are using a response service.