Short answer: No.
By design, Cassandra values availability and partition tolerance over consistency1. Basically, it's not possible to get acceptable latency while maintaining all three of qualities: one has to be sacrificed. This is called CAP theorem.
The amount of consistency is configurable in Cassandra using consistency levels, but there doesn't exist any semantics for rollback. There's no guaranty that you'll be able to roll back your changes even if the first write succeeds.
If you wan't to build application with transactions or locks on top of Cassandra, you probably want to look at Zookeeper, which can be used to provide distributed synchronization.
You might've already guessed this, but Cassandra doesn't have foreign keys or anything like that. This has to be handled manually. I'm not that familiar with Hector, but a higher-level client could be able to do this semi-automatically.
Whether or not you can use Cassandra to easily replace a RDBMS depends on your specific use case. In your use case (based on your questions), it might be hard to do so.