As Peter M said, test it.
There isn't a real enough calculation you can perform which will give you enough information to work off of.
The reality is that there are too many variables to consider. For example:
What actual rate do the NIC's involved transfer at? Note that this rate will be different based on which network cards are in place as well as which DRIVERS those cards are using. You could quite easily have a 1Gb card which can only transfer at, say, 300Mb due to driver issues. I've even seen two cards by the exact same manufacturer with the same drivers have different transfer speeds due to a slight configuration difference in one of the cards.
What other pieces of equipment are between the two machines in question? Again, depending on the hardware, os's etc, you may see wildly different numbers. A $100 8 port 1Gb unmanaged switch from TRENDNet is going to have completely different throughput than a $5000 1Gb cisco managed switch.
You will also have to consider the existing network "weather" at the time of the transfer What is the throughput from OTHER network traffic over the same lines that this will share. This will be a transient factor as the existing network load changes as different demands are placed on it.
Additionally, some nic's support TCP Offloading, others don't. If your nic's don't then effective transfer rate is going to be hampered by whatever else the CPUs on those boxes are doing.
Next, hard drives have to be taken into consideration. Considering this is a large amount of data, then the read and write speeds of the various hard drives will have an impact. Sure the network might actually be able to run at 90% efficiency, but if you are talking large amounts of data, the hard drives themselves might not be able to keep up and therefore cause that to drop down to 25% efficiency, or less.
Point is, you have to test it and at the end of the day, the protocol that SQL server uses will be immaterial to your findings. And don't run just one test, run a lot of real world tests. Only then will you be able to come up with an average; which might still be off depending on whatever else is going on at the time, but you should be able to get within say 10%.