What advices do you have to handle the boss ?
First make sure you have a good analysis document and that you have for every dependency a spoc (single point of contact). Make sure the people who you're making this application for are integrated into the process. I suggest using something like scrum but certainly daily standup meetings.
Use a good system to follow up on everyone like for example TFS2010 which has also testing capabilities integrated so your testing team can be better integrated.
Have a bug tracking tool and source safe handy. Continuous integration is also an asset.
but gives me inexperienced staff that don't even know to program on ASP.NET
It's your boss intention to upgrade his people to a level where they are capable of programming ASP.NET applications in the end. What way to better learn it than hands on experience from a dedicated professional like you?
Be aware: you're dealing with people now, not just code. They get sick, have their strenghts and weaknesses just like you. And believe me, it can be a challenge sometimes to deal with the human part of a project. Especially when there's pressure due to release dates.