I'm not going to quibble with "I think" or "maybe" -- you can not do this with a Regex.
Matching against a regex can validate that the form of the input is correct, and can also be used to extract pieces of the input, but it can not do value comparisons, or duplicate elimination (except in limited well defined circumstances), or range checking.
What you have as input I interpret as a comma-separated list of values or ranges of values; in BNFish notation:
value :: number
range :: value '-' value
term :: value | range
list :: term [','term]*
A regex can be built that will match this to verify correct structure, but you'll have to do other validation for the value comparisons and to prevent the duplicate numbers.
The most straigtforward regex I can think of (on short notice) is this
([0-9]+|[0-9]+-[0-9]+)(, *([0-9]+|[0-9]+-[0-9]+))*
You have digits or digits-digits, optionally followed by comma[optional space](digits or digits-digits) - repeated zero or more times.
I tested this regex at http://www.fileformat.info/tool/regex.htm with the input 3,4-12,6,2,90-221
Of course you can replace the [0-9] with [\d] for regex dialects that allow it.