I think you're being quite ambitious in trying to apply a new technique to a project that's under such tight deadlines that you can't take the time to study the technique in detail.
At a high level DDD is about decomposing your solution into layers and allocating responsibilities cleanly. If you attempt just to do that in your application you're likely to get some benefit. Later, when you have more time to study, you may discover that you didn't quite follow all the details of the DDD approach - I don't see that as a problem, you proabably already got some benefit of thoughtful structure even if you deviated from some of the DDD guidance.
To specifically answer your question in detail would just mean reiterating material that's already out there: Seems to me that this document nicely summarises the terms you're asking about.
They say about Services:
Some concepts from the domain aren’t
natural to model as objects. Forcing
the required domain functionality to
be the responsibility of an ENTITY or
VALUE either distorts the definition
of a model-based object or adds
meaningless artificial objects.
Therefore: When a significant process
or transformation in the domain is not
a natural responsibility of an ENTITY
or VALUE OBJECT, add an operation to
the model as a standalone interface
declared as a SERVICE.
Now the thing about this kind of wisdom is that to apply it you need to be able to spot when you are "distorting the definition". And I suspect that only with experience (or guidance from someone who is experienced) do you gain the insight to spot such things.
You must expect to experiment with ideas, get it a bit wrong sometimes, then reflect on why your decisions hurt or work. Your goal should not be to do DDD for its own sake, but to produce good software. When you find it cumbersome to implement something, or difficult to maintain something think about why this is, then examine what you did in the light of DDD advice. At that point you may say "Oh, if I had made that a Service, the Model would be so nmuch cleaner", or whatever.
You may find it helpful to read an example.: