If you only have those distinct values in the field, then you can just use a dictionary to translate the strings into suitable numbers, like this:
var order = new Dictionary<string, int>();
order.Add("S", 0);
order.Add("P", 1);
order.Add("NB", 2);
order.Add("V", 3);
order.Add("Nc", 4);
repeater.DataSource = query.OrderBy(p => order[p.Title]);
If the source is LINQ to SQL, you would have to realise it into a list first, so that you are using LINQ to Objects to do the sorting:
repeater.DataSource = query.ToList().OrderBy(p => order[p.Title]);