The simplest way would be to simply store the entire contents of the file in memory until you are finished, write out the header, and then write out the rest of the file.
If memory is an issue and you can't safely store the entire file in memory, or just don't want to, then you could write out the bulk of the CSV data to a temporary file, then when you are finished, write the header out to the primary file, and copy the data from the temporary file to the primary file in a loop.
If you wanted to be fancy, after writing the main CSV data out to the primary file, you could loop through the file from the beginning, read into memory the data that you're about to overwrite with the header, then write the header over top of that data, and so forth, read each chunk into memory, overwrite it with the previous one until you reach the end and append the final chunk. In this way you "insert" data at the beginning, my moving the rest of the file down. I really wouldn't recommend this as it will mostly just add complexity without much benefit, unless there is a specific reason you can't do something simpler like using a temporary file.