I would add the namespace to the imports so you don't have to type it every time:
Imports System.Runtime.CompilerServices
<Extension()> _
Public Sub Test(ByVal Value As String)
End Sub
Once you have it in your imports you can just add Extension to the top of every method instead of the whole thing.
As shahkalpesh said you extension method is incomplete you will need to add the type you want to extend(see code first parm). I just had a play and found that if you don't supply a type to extend as a parameter the complier will throw an error.