Dartmouth BASIC was designed to be easy to learn and easy to use. For what it did, it was a howling success on both counts.
MIT used Scheme (dialect of LISP) in course 6.001 for many years, and concluded that it was a lot easier to learn, at least initially, because there was essentially no syntax to trip students up.
Back in the late Steam Era, when mainframe dinosaurs still ruled the Earth, the UT Austin Computer Science Department did side-by-side tests, teaching FORTRAN to some of the freshman and PASCAL to others. Their conclusion was that PASCAL's pickier syntax was INITIALLY harder to learn, but the PASCAL students consistently spent less computer time, and less runs (batch processing, punched cards), getting their homework running, even though their homework assignments were typically harder.
C and C++ have very, very similar core languages. 90% of the code you write will be identical in all four languages, after allowing for personal taste in design and naming conventions. C doesn't really have anything above the core language, while C++ adds classes and templates. I'm not familiar with C# or Java, beyond a rudimentary feeling that they both started with C and went from there.
Ada was, in my personal experience, not difficult to learn, and the compilers were picky enough that syntactically-correct code generally worked as intended on the first try. Other people have also noticed that property of Ada.