Further to Kyle's answer, I would strongly recommend against trying to use the Posix subsystem in Windows. It's implemented to an absolute bare minimum level such that Microsoft can claim "Posix support" on a feature sheet tick box. Perhaps somebody out there actually uses it, but I've never encountered it in real life.
One can certainly write cross-platform C code, you just have to be aware of the differences between platforms, and test, test, test. Unit tests and a CI (continuous integration) solution will go a long way toward making sure your program works across all your target platforms.
A good approach is to isolate the system-dependent stuff in one or a few modules at most. Provide a system-independent interface from that module. Then build everything else on top of that module, so it doesn't depend on the system you're compiling for.