I started off with php and mysql, it's a lower-level then the rest of the environments like Django and Ruby on Rails; so it's much easier to understand what is really happening.
If you want to get into web development, php is a solid foundation and has easy bundle installers such as WAMP, and has a massive community.
However if understanding the core of web applications is not your goal and you want some magic to make your application quicker and speed through development, you would want to use a web application framework environment, my favorite here is Ruby on Rails.
Ruby on Rails is a little difficult for the newbie to setup, it typically sucks running in Windows, so you'd be better off with an install on top of a UNIX environment such as Linux, Mac OS, BSD.
If you do want to go the rails route, I suggest installing Ruby with a ruby manager called RVM which is very helpful for playing around with Ruby environments.
Django is a good solid framework but it's playing catch up with Rails and in my honest opinion, doesn't have all those power magic that Rails has such as database migrations.